THE GENESIS OF THE CENTRAL
WALES OREFIELD
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INTRODUCTION
Mining has taken place in Central
Wales since Bronze Age times (for copper); later mining
was for lead and silver (Elizabethan and Civil War times)
and zinc became important from the mid-19th century
onwards. Modest amounts of marcasite and barium minerals
have been produced locally and one mine has been looked
at as a calcite resource. Mining ceased in the early 20th
century, but much research has since been undertaken,
with a host of unusual ore minerals being identified from
the mid-1980s onwards. The
Orefield is a polyphase mineralised terrain. The
mineralisation is epigenetic vein-type and at least
twelve episodes of fracturing and mineralisation,
represented by successive crosscutting mineral
assemblages, have been identified. The mineralisation is
entirely hosted by Upper Ordovician to Lower Silurian
clastic marine sediments.
The veins are all post-Acadian in age, with a range of
isotopic ages suggesting emplacement from Devonian
through to Permian times. The mineralisation is therefore
very different from the pre-tectonic metallogenic
province known as the Dolgellau Gold-belt, only a short
distance to the north. The Gold-belt, however, is hosted
by a highly altered suite of Cambrian sediments and
intrusives: the paragenetic and alteration patterns are
completely different and the veins themselves have been
folded and boudinaged.
The veins of Central Wales are dominated by quartz with
two major generations of carbonate, the early one being
ferroan dolomite and the later one calcite. Baryte and
witherite are late-stage components in the eastern part
of the orefield. Fluorite is absent so far as we know.
Sulphides are locally abundant and may form large masses
or ribs. Galena and sphalerite are broadly speaking the
most abundant, with lesser chalcopyrite and tetrahedrite
and locally important very late marcasite. A wide range
of accessory ore minerals, particularly cobalt and
nickel-bearing species, occur in certain assemblages.
The paragenetic determinations that allowed the
assemblages to be determined as set out in the table
below were based on basic principles involving fracturing
and rebrecciation. A frequent feature in Central Wales is
to find one assemblage occurring in a vein crosscutting
another, or to find one assemblage rebrecciated and
cemented by another. In such cases it is straightforward
to say that one came first, the other later. Moreover
regional patterns, in which such observations repeat
themselves time and again, tend to build up as more sites
are studied.

Above: a view of part of
Cwmystwyth mine, one of the larger mines of Central
Wales, where extraction of ores has intermittently
occurred since the Bronze Age. Several of the twelve
Central Wales mineral assemblages may be identified here.
The twelve assemblages I have divided (in my MPhil thesis
& later publications) into Early (A1) and late (A2).
The suggested ages are based on a lead isotope study
using paragenetically selected galena samples that I did
with geochemists at the British Geological Survey in the
late 1980s. The model isotopic ages were certainly
consistent with the "paragenetic relative ages"
of the assemblages. The "paragenetically last"
Central Wales assemblage - the A2-f marcasite assemblage,
has not been studied isotopically - no galena! If the
Pb-Pb dates are correct this would pont to a major
mineralising event occurring in post-Permian times.
Interestingly some of the later Central Wales assemblages
with consistent Permian Pb-Pb dates are texturally very
similar to the MVT assemblages of the UK Pennine
Orefields, and we know from evidence exposed at Ogmore in
South Wales that the hydrothermal activity responsible
for these MVT deposits continued at least into Lower
Jurassic times and quite possibly beyond. For example, at
Witches Point near Southerndown on the Bristol Channel
coast, there is a thick iron sulphide-calcite vein which
has undergone cataclasis during the mid-Tertiary Alpine
earth-movements: the smashed pyrite is crosscut by veins
of undeformed galena and sphalerite indicating
geologically very young Pb-Zn mineralisation. As ever,
further work is required!

Above: Central Wales
features, in addition to the more typical Pb-Zn-Cu ores,
a number of unusual metalliferous minerals, and
particularly several species containing nickel and
cobalt. This is a sample, magnified x1.5, of pinkish grey
metallic siegenite (Ni,Co)3S4
associated with brassy yellow chalcopyrite in
quartz-cemented breccia.
The table below gives details of the primary paragenesis.
The assemblages are listed in order of deposition as are
the minerals in each assemblage. Species underlined are
major economic components, those in italic only occur in
trace amounts; the rest are minor phases occurring at
more than two localities.
A1
("Early complex") assemblages:
"Complex" because of the mineral
diversity and often fine grainsize - ore
petrology absolutely vital in their paragenetic
study. The A1-C assemblage is very likely to
yield many more species with further study.
Mainly as breccia-cements dominated by tough,
compact milky quartz rdaially grown about rock
clasts. Wall-rock alteration is subtle. Early
Devonian isotopic age: formed during
post-Caledonian relaxation.
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A1-a:
Minor early Cu; weak brecciation
Minerals: quartz + chalcopyrite + ferroan
dolomite
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A1-b:
Early sphalerite assemblage; brecciation
quartz + pyrite + sphalerite
(with chalcopyrite disease)
+ ferroan dolomite + chlorite
Examples: Castell and
Erglodd mines
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A1-c:
Polymetallic assemblage; great mineralogical
diversity accompanied by major brecciation. The
assemblage that supported the silver-mining
industry of the 16th-17th centuries, due to its
locally significant argentiferous tetrahedrite
component.
quartz + pyrite + siegenite + cobalt
pentlandite + millerite + chalcopyrite
+ pyrrhotite
+ tucekite + ullmannite + gersdorffite
+ electrum
+ tetrahedrite
+ bournonite + boulangerite
+ galena
Examples: Erglodd, Darren,
Esgairhir, Eaglebrook, Brynyrafr mines
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A1-d:
Minor late veining, often cutting sheared
sulphides e.g. "steel ore" galena.
chalcopyrite + galena + "honey-blende"
sphalerite |
A1-e:
Ferroan dolomite influx - copious quantities of
carbonate which cement rebrecciated A1-C and
older material
quartz + ferroan dolomite
Examples: Esgairfraith,
Eaglebrook, Hafan mines
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A1-f:
Late cavity-filling: widespread in minor to trace
amounts - forms fracture-veins cutting ferroan
dolomite too
quartz + siegenite + cobalt pentlandite +
millerite + chalcopyrite + galena
Examples: Eaglebrook and
Henfwlch mines |
A2
("Late simple") assemblages:
"Simple" because of the coarse and
largely inclusion-poor sulphide grains.
Both breccia-cements and crustiform open-space
fillings; the quartz is glassy-white to clear and
tends to be vuggy. Wall-rock alteration
noticeable in A2-b, A2-d and A2-f assemblages
where silicification has occurred to a modest
extent. Early Carboniferous to Permian isotopic
ages: formed mainly during pre- and post-Variscan
extension during basin development.
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A2-a:
Major Pb-Zn assemblage; major brecciation.
Assemblage gave large-tonnage orebodies with
abundant Pb-Zn and low Ag grades characteristic.
quartz + sphalerite
+ chalcopyrite + galena
Examples: Frongoch,
Cwmystwyth, Van mines
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A2-b:
Coarse-grained (to 10mm) ullmannite-bearing Pb-Cu
assemblage; major brecciation & open
fracture-filling
quartz + chalcopyrite
+ ullmannite + galena
Examples: Dolclettwr,
Goginan, Cefngwyn mines |
A2-c:
Calcite-dominated assemblage; primarily
crustiform-banded open fissure-fill
quartz + galena
+ sphalerite
+ calcite
+ chalcopyrite + pyrite
Examples: Dolclettwr and
Nantiago mines
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A2-d:
Coarsely crystalline quartz; large (to 15cm),
always well growth-zoned quartz xls with
dendritic iron sulphide and chalcopyrite
inclusions - open space filling
quartz + chalcopyrite + pyrite
Examples: Frongoch,
Cefngwyn, Nantymwyn mines
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A2-e:
Barium minerals assemblage; brecciation, gouging
and open fissure-fill, localised but large
quantities of minerals where developed
quartz
+ sphalerite + galena + calcite + baryte
+ witherite
Examples: Bryntail,
Penyclun, Gorn mines and an isolated trial to the
W of Esgairhir.
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A2-f:
Iron sulphides assemblage: widespread and locally
in major quantities causing post-mining
environmental problems. Emplacement accompanied
both by brecciation and open fissure-fill.
quartz + sphalerite + pyrite + marcasite
Examples: Brynyrafr and
Cwmrheidol mines
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IMAGE MENU:
The images in the menu above
cover some of the more interesting ore minerals from
Central Wales. For the uninitiated, apart from the
breccias page, these images are taken through a
high-power microscope which views the samples in
reflected light. Each sample is a block of opaque ore
minerals that has been painstakingly polished to an
optical mirror-finish using diamond pastes down to 1
micron in size.
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