J.S. Mason - Central Wales Orefield:
Tetrahedrite,
bournonite and ullmannite
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Until relatively recently,
the
importance of tetrahedrite ((Cu,Ag)10(Fe,Zn)2Sb4S13)
in
parts of Central Wales was not appreciated. As
the formula suggests, however, it is a significant silver carrier! It
is restricted in occurrence to the early, A1-c assemblage, where its
common associates are galena, chalcopyrite, bornonite, siegenite,
ullmannite, gersdorffite and milky quartz. Tetrahedrite is a
significant part of that assemblage in the Talybont district and,
particularly, at the mines between Darren and Goginan where very high
silver yields (~30 ounces/ton) in lead-ore concentrates were par for
the course. Not surprisingly, these ores consistently contain
inclusions of richly argentiferous tetrahedrite (ca. 18wt% Ag from
electron microprobe analyses).
In this image, tetrahedrite forms grey-brown triple-grain contact
inclusions in recrystallised galena with chalcopyrite (yellow) and a
little white ullmannite. The sample is from Cwmerfin mine and is fairly
typical for the Darren-Goginan district. Tetrahedrite also occurs
visibly in hand specimens as 2-3 cm aggregates and its presence must
have been known about in the 17th century - these were silver mines
back then.
Tetrahedrite is isotropic, a feature that makes it distinguishable
under crossed polars from the otherwise rather similar (but greyer)
bournonite (below).
Bournonite has moderate
anisotropy, featuring brownish and bluish polarisation colours.
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Bournonite (L)
always accompanies tetrahedrite, and in this photograph, a little
ullmannite (NiSbS) - white, less scratched - is also present. Like
tetrahedrite, bournonite may form larger, visible aggregates to 2-3cm
across, distinguishable with care from tetrahedrite by their poorly
developed cleavage (tetrahedrite always breaks with a conchoidal
fracture). This sample is from Erglodd mine, Talybont.
10-50 micron ullmannite inclusions crowd galena samples from the A1-c
assemblage as seen both in the Talybont district and at the
Darren-Goginan mines. They were originally thought by a previous worker
(Raybould, 1974 - see bibliography page accessible from Geology
page) to be
arsenopyrite. The electron microprobe sorted that one out! Arsenopyrite
has not been identified in these mines so far: the only confirmed
arsenide is gersdorffite (NiAsS) which has been identified at the
Darren-Goginan mines. It is much rarer than ullmannite.
The
later A2-b
assemblage also carries ullmannite, but this time it occurs visibly as
cubic crystals to 1cm, associated with chalcopyrite and galena - the
latter often overgrowing it epitaxially, accompanied by clear
crystalline quartz.
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